9-(Biphenyl-4-yloxycarbonyl)-10-methylacridinium trifluoromethanesulfonate

被引:4
|
作者
Trzybinski, Damian [1 ]
Skupien, Magdalena [1 ]
Krzyminski, Karol [1 ]
Sikorski, Artur [1 ]
Blazejowski, Jerzy [1 ]
机构
[1] Univ Gdansk, Fac Chem, PL-80952 Gdansk, Poland
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
CHEMILUMINESCENCE;
D O I
10.1107/S1600536809007569
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title compound, C27H20NO2+center dot-CF3SO3-, the cations form inversion dimers through pi-pi interactions between the acridine ring systems [centroid-centroid distances = 3.668 (2)-3.994 (2) angstrom]. These dimers are further linked by C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions. The cation and the anion are connected by C-H center dot center dot center dot O interactions. The mean plane of the acridine ring system makes dihedral angles of 10.6 (1) and 82.5 (1)degrees, respectively, with the adjacent phenyl ring and the carboxy group. The two phenyl rings of the biphenyl group are oriented at 42.9(1)degrees.
引用
收藏
页码:O770 / U2126
页数:14
相关论文
共 50 条