Modulating H2 sorption in metal-organic frameworks via ordered functional groups

被引：10

作者：

Dau, Phuong V. ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 81期

关键词：

HYDROGEN STORAGE; ADSORPTION; PORE;

D O I：

10.1039/c4cc05265j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we present the use of presynthetic and postsynthetic modification (PSM) approaches to regulate the structural organization of functional groups in the pores of isoreticular metal-organic frameworks (IRMOFs). It has been found that the structural ordering of aryl groups within the IRMOF pores results in hysteretic H-2 sorption, while the same aryl groups introduced in a disordered manner displays reversible H-2 sorption that is more typical of the IRMOF family.

引用

页码：12154 / 12157

页数：4

共 50 条

[1] Modulating H2 sorption of metal-organic frameworks via ordered functional groups
Dau, Phuong V.
Cohen, Seth M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[2] Metal-organic frameworks for H2 storage
Wei, Zhangwen
Zhou, Hongcai
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[3] Effect of Functional Groups on the I2 Sorption Kinetics of Isostructural Metal-Organic Frameworks
Lee, Byeongchan
Park, Jinhee
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2021, 42 (02) : 290 - 293
[4] Mapping of Functional Groups in Metal-Organic Frameworks
Kong, Xueqian
Deng, Hexiang
Yan, Fangyong
Kim, Jihan
Swisher, Joseph A.
Smit, Berend
Yaghi, Omar M.
Reimer, Jeffrey A.
SCIENCE, 2013, 341 (6148) : 882 - 885
[5] On the nature of the interaction between H2 and metal-organic frameworks
Kuc, Agnieszka
Heine, Thomas
Seifert, Gotthard
Duarte, Helio A.
THEORETICAL CHEMISTRY ACCOUNTS, 2008, 120 (4-6) : 543 - 550
[6] Entropy prediction for H2 adsorption in metal-organic frameworks
Liu, Yu
Guo, Fangyuan
Hu, Jun
Zhao, Shuangliang
Liu, Honglai
Hu, Ying
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (34) : 23998 - 24005
[7] Screening of hypothetical metal-organic frameworks for H2 storage
Gomez, Diego A.
Toda, Jordi
Sastre, German
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (35) : 19001 - 19010
[8] On the nature of the interaction between H2 and metal-organic frameworks
Agnieszka Kuc
Thomas Heine
Gotthard Seifert
Hélio A. Duarte
Theoretical Chemistry Accounts, 2008, 120 : 543 - 550
[9] Conductive metal-organic frameworks for electrocatalytic H2 evolution
Marinescu, Smaranda
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
[10] Grafting functional groups in metal-organic frameworks for U(VI) sorption from aqueous solutions
Xiong, Jianbo
Fan, Yaling
Luo, Feng
DALTON TRANSACTIONS, 2020, 49 (36) : 12536 - 12545

← 1 2 3 4 5 →