Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide

被引：1502
|
作者：
Nikolaev, P [1 ]
Bronikowski, MJ [1 ]
Bradley, RK [1 ]
Rohmund, F [1 ]
Colbert, DT [1 ]
Smith, KA [1 ]
Smalley, RE [1 ]
机构：
[1] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA
来源：
CHEMICAL PHYSICS LETTERS | 1999年 / 313卷 / 1-2期
基金：
美国国家航空航天局;
关键词：
D O I：
10.1016/S0009-2614(99)01029-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Single-walled carbon nanotubes (SWNTs) have been produced in a gas-phase catalytic process. Catalysts for SWNT growth form in situ by thermal decomposition of iron pentacarbonyl in a heated flow of carbon monoxide at pressures of 1-10 atm and temperatures of 800-1200 degrees C. The SWNT yield and diameter distribution can be varied by controlling the process parameters, and SWNTs as small as 0.7 nm in diameter, the same as that of a C-60 molecule, have been generated. This process shows great promise for bulk production of carbon nanotubes. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：91 / 97
页数：7
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