Efficient copper-catalyzed amination of aryl halides with amines and N-H heterocycles using rac-BINOL as ligand

被引：62

作者：

Zhu, Di ^{[1
]}

Wang, Rongliang ^{[1
]}

Mao, Jincheng ^{[1
]}

Xu, Lei ^{[1
]}

Wu, Fan ^{[1
]}

Wan, Boshun ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 256卷 / 1-2期

关键词：

Amination; copper; aryl halides; cross-coupling; rac-BINOL; ligand;

D O I：

10.1016/j.molcata.2006.05.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly efficient copper-catalyzed system using commercially available racemic 1,1'-binaphthyl-2,2'-diol (rac-BINOL) as the ligand was developed for amination of aryl halides and heteroaryl halides with alkyl amines and N-H heterocycles. Good to high yields were obtained for aryl bromides and heteroaryl chlorides. The commercially available rac-BINOL ligand with excellent stability and high efficiency for aryl bromides and heteroaryl chlorides ultimately make this protocol of potentially practical utility. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：256 / 260

页数：5

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