Synthesis, characterization, and properties of polychelates of poly(styrene sulfonic acid-co-maleic acid) with Co(II), Cu(II), Ni(II), and Zn(II)

被引：30

作者：

Rivas, BL

Seguel, GV

Geckeler, KE

机构：

[1] Univ Concepcion, Fac Chem, Concepcion, Chile

[2] Kwangju Inst Sci & Technol, Dept Mat Sci & Engn, Lab Appl Macromol Chem, Puk Gu, Kwangju 500712, South Korea

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2002年 / 85卷 / 12期

关键词：

water-soluble polymers; metal ions; polychelates; semiempirical calculations;

D O I：

10.1002/app.10862

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymer metal complexes of poly(styrene sulfonic acid-co-maleic acid) and Cu(II), Ni(II), Co(II), and Zn(II) were synthesized. The magnetic, spectral, and thermal properties, as well as the electrical conductivities, of the chelates were investigated, and possible structures were assigned to the polychelates. Semiempirical calculations at the AMI level were carried out on the geometrical arrangement of the polychelates. (C) 2002 Wiley Periodicals, Inc.

引用

页码：2546 / 2551

页数：6

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