Access to Functionalized Luminescent Multi-2,2′:6′,2"-terpyridine Ligands

被引：5
|
作者：
Jacques, Alexandre [1 ]
Cerfontaine, Simon [1 ]
Elias, Benjamin [1 ]
机构：
[1] Catholic Univ Louvain, IMCN, Mol Solides & React MOST, B-1348 Louvain La Neuve, Belgium
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 21期
关键词：
ORGANOMETALLIC SHEETS; TERPYRIDINE LIGAND; COPOLYMERS; ACID;
D O I：
10.1021/acs.joc.5b01897
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A one-pot synthesis of substituted multi-2,2':6',2 ''-terpyridines (multi-tpy) has been achieved using an acetylquaterpyridine precursor with various aryl aldehydes in basic media. This strategy enables ready access to functionalized terpyridines. Utilizing a Suzuki-type cross-coupling, larger structures such as tetra- or even hexa-tpy were obtained from our tri-tpy precursor. These macromolecular units are ideal building blocks for the construction of transition-metal-based supramolecular assemblies.
引用
收藏
页码：11143 / 11148
页数：6
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