Synthesis, crystal structure, and fluorescent property of a 1D Pb(II) coordination polymer containing unique helical chains based on 4,4′-oxydiphthalate

被引：1

作者：

Wang, Jun ^{[1
]}

Ju, Wen-Wen ^{[1
]}

Xue, Yun-Shan ^{[1
]}

Tao, Jian-Qing ^{[1
]}

机构：

[1] Yancheng Teachers Univ, Sch Chem & Chem Engn, Yancheng 224002, Jiangsu, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 04期

关键词：

Crystal structure; coordination polymer 4,4 '-oxydiphthalic acid; luminescence; METAL-ORGANIC FRAMEWORKS; N-DONOR LIGANDS; LUMINESCENT PROPERTIES; COMPLEXES; 3,3',4,4'-OXYDIPHTHALATE; TEMPERATURE; ZINC(II); SERIES;

D O I：

10.1080/15533174.2016.1186073

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A one-dimensional Pb(II) complex [Pb-2(H2ODPT)(2)(H2O)(7)center dot H2O](n) (1) (H4ODPT = 4,4'-Oxydiphthalic acid) has been synthesized and characterized using single crystal X-ray diffraction, IR, and elemental analysis. Single-crystal X-ray diffraction analysis revealed that complex 1 is a one-dimensional chain polymer containing unique helical chains. Adjacent 1D chains are linked by pi-pi interaction, intermolecular and intramolecular O-H center dot center dot center dot O hydrogen bonds to form a three-dimensional supramolecular structure. The thermal stability and photoluminescent property of the title complex have been investigated.

引用

页码：488 / 492

页数：5

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