Procedure-dependent construction of two isomers of trimeric self-assembled boronic esters

被引:12
|
作者
Ono, Kosuke [1 ,2 ]
Aizawa, Ryo [1 ,2 ]
Yamano, Taiki [1 ,2 ]
Ito, Suguru [1 ,2 ]
Yasuda, Nobuhiro [3 ]
Johmoto, Kohei [2 ,4 ]
Uekusa, Hidehiro [2 ,4 ]
Iwasawa, Nobuharu [1 ,2 ]
机构
[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan
[2] Japan Sci & Technol Agcy JST, CREST, Tokyo 1528551, Japan
[3] Japan Synchrotron Radiat Res Inst Spring 8, Sayo, Hyogo 6795198, Japan
[4] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan
基金
日本科学技术振兴机构;
关键词
COVALENT CHEMISTRY; POROUS MATERIALS; CAGE; FUNCTIONALIZATION;
D O I
10.1039/c4cc05836d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A procedure-dependent selective construction of two isomers of trimeric boronic esters was realized. A capsule-like trimeric boronic ester was constructed by the direct connection of two kinds of self-assembled boronic esters via [3+2] cycloaddition, while the tricyclic trimeric boronic ester was obtained by the self-assembly of pre-connected components.
引用
收藏
页码:13683 / 13686
页数:4
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