Molecular rheology of glassy polymers

被引:0
|
作者
Osaki, K [1 ]
Inoue, T [1 ]
机构
[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
来源
MOLECULAR INTERACTIONS AND TIME-SPACE ORGANIZATION IN MACROMOLECULAR SYSTEMS | 1999年
关键词
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Simultaneous measurements of stress and birefringence in oscillatory deformation were revealed to provide information on the deformation of polymer chains and origin of stress in glassy state. The stress was composed of the glassy stress similar to that of ordinary glass-forming liquids and the rubbery stress due to the entropic force of chains. The relaxation behavior of these stress components were discussed in details.
引用
收藏
页码:67 / 70
页数:4
相关论文
共 50 条
  • [11] Rheology and molecular weight distribution of hyperbranched polymers
    Suneel
    Buzza, DMA
    Groves, DJ
    McLeish, TCB
    Parker, D
    Keeney, AJ
    Feast, WJ
    MACROMOLECULES, 2002, 35 (25) : 9605 - 9612
  • [12] MOLECULAR RHEOLOGY OF FLEXIBLE POLYMERS - EXPERIMENT AND THEORY
    GRAESSLEY, WW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 184 (SEP): : 1 - POLY
  • [13] A MOLECULAR INTERPRETATION OF THE TOUGHNESS OF GLASSY-POLYMERS
    BROWN, HR
    MACROMOLECULES, 1991, 24 (10) : 2752 - 2756
  • [14] Molecular analysis of the dissolution of glassy polymers.
    Narasimhan, B
    Peppas, NA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 264 - PMSE
  • [15] MOLECULAR-CONFORMATION IN MOLTEN AND GLASSY POLYMERS
    LINDENMEYER, PH
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1973, B008 (1-2): : 361 - 366
  • [16] Dissolution mechanism of glassy polymers: A molecular analysis
    Narasimhan, B.
    Peppas, N.A.
    ACS Symposium Series, 710 : 413 - 432
  • [17] MOLECULAR MECHANISM FOR DEFORMATION IN GLASSY AND RUBBERLIKE POLYMERS
    YANNAS, IV
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1975, 20 (03): : 402 - 402
  • [18] The molecular basis of fracture in crosslinked glassy polymers
    Sambasivam, M
    Klein, A
    Sperling, LH
    JOURNAL OF APPLIED POLYMER SCIENCE, 1997, 65 (05) : 1001 - 1011
  • [19] Molecular basis of fracture in crosslinked glassy polymers
    Lehigh Univ, Bethlehem, United States
    J Appl Polym Sci, 5 (1001-1011):
  • [20] Fracture in glassy polymers: a molecular modeling perspective
    Rottler, Joerg
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2009, 21 (46)