New Cobalt and Zinc Complexes with Schiff Base Ligands: Synthesis, Structures, and Biochemical Properties

被引：0
|
作者：
Liu, Hai-Yan [1 ]
Li, Chao [1 ]
Ma, Jing-Jun [1 ]
机构：
[1] Agr Univ Hebei, Coll Sci, Hebei Key Lab Bioinorgan Chem, Baoding 071001, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 01期
关键词：
Biochemical property; cobalt complex; crystal structure; Schiff base; zinc complex; TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURES; ANTIMICROBIAL ACTIVITIES; COPPER(II) COMPLEXES; NI(II); CO(II);
D O I：
10.1080/15533174.2013.819904
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two similar Schiff base ligands 2-[(2-isopropylaminoethylimino) methyl]-5-methoxyphenol (HLa) and 2-ethoxy-6-[(2-isopropylaminoethylimino) methyl] phenol (HLb) reacting with cobalt perchlorate and zinc iodide, respectively, in methanol gave the complexes [CoL2a]center dot ClO4 (1) and [Zn(HLb)(2)I-2(m-OH)]center dot I center dot MeOH (2). Both complexes were characterized by elemental analyses and IR spectroscopic method in the solid state. Single-crystal X-ray analysis was performed, which reveals that (1) is a mononuclear cobalt complex, and (2) is a dinuclear zinc complex. The Co atom in (1) is in an octahedral coordination. The Zn atoms in (2) are in tetrahedral coordination. Antibacterial activities of the Schiff base ligands and the complexes have been studied on the strains B. subtilis, E. coli, and S. aureus.
引用
收藏
页码：127 / 132
页数：6
相关论文
共 50 条
  • [41] Synthesis and Characterization of Two New Schiff Base Ligands and their Complexes with Cobalt(II), Nickel(II) and Copper(II)
    Ayşegül Yazicı
    Filiz Akgün
    Transition Metal Chemistry, 2006, 31 : 152 - 156
  • [42] Synthesis and characterization of some new Schiff base ligands and their complexes with cobalt(II), nickel(II) and copper(II)
    Haghgooie, Hossein
    Oskoui, Maryam Saket
    ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (08) : 6081 - 6089
  • [43] Synthesis and characterization of two new schiff base ligands and their complexes with cobalt(II), nickel(II) and copper(II)
    Yazici, A
    Akgün, F
    TRANSITION METAL CHEMISTRY, 2006, 31 (02) : 152 - 156
  • [44] Synthesis and crystal structures of Schiff base zinc(III) complexes with antibacterial activity
    Zhang, J.
    Pan, F.
    Cheng, H.
    Du, W.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (07) : 514 - 519
  • [45] Synthesis and crystal structures of Schiff base zinc(III) complexes with antibacterial activity
    J. Zhang
    F. Pan
    H. Cheng
    W. Du
    Russian Journal of Coordination Chemistry, 2010, 36 : 514 - 519
  • [46] Synthesis, characterization, luminescent properties and biological activities of zinc complexes with bidentate azomethine Schiff-base ligands
    Burlov, A. S.
    Vlasenko, V. G.
    Koshchienko, Yu, V
    Makarova, N., I
    Zubenko, A. A.
    Drobin, Yu D.
    Fetisov, L. N.
    Kolodina, A. A.
    Zubavichus, Ya, V
    Trigub, A. L.
    Levchenkov, S., I
    Garnovskii, D. A.
    POLYHEDRON, 2018, 154 : 65 - 76
  • [47] Synthesis, Structures, and Antimicrobial Activity of Schiff Base Zinc Complexes with Thiocyanate and Iodide
    Xue, Ling-Wei
    Zhao, Gan-Qing
    Han, Yong-Jun
    Feng, Yun-Xiao
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2011, 41 (02) : 141 - 146
  • [48] Synthesis, crystal structures, spectroscopic studies and antibacterial properties of a series of mononuclear cobalt(III) Schiff base complexes
    Hasanzadeh, Maryam
    Salehi, Mehdi
    Kubicki, Maciej
    Shahcheragh, Seyyed Mohammad
    Dutkiewicz, Grzegorz
    Pyziak, Mikoaj
    Khaleghian, Ali
    TRANSITION METAL CHEMISTRY, 2014, 39 (06) : 623 - 632
  • [49] A series of mononuclear lanthanide complexes constructed by Schiff base and β-diketonate ligands: synthesis, structures, magnetic and fluorescent properties
    Ge, Yu
    Huang, Yuan
    Wang, Guoqing
    Li, Yahong
    Yao, Jinlei
    POLYHEDRON, 2020, 187
  • [50] Synthesis, crystal structures, spectroscopic studies and antibacterial properties of a series of mononuclear cobalt(III) Schiff base complexes
    Maryam Hasanzadeh
    Mehdi Salehi
    Maciej Kubicki
    Seyyed Mohammad Shahcheragh
    Grzegorz Dutkiewicz
    Mikołaj Pyziak
    Ali Khaleghian
    Transition Metal Chemistry, 2014, 39 : 623 - 632
12345