Catalytic Olefin Polymerization Process Modeling: Multi-Scale Approach and Modeling Guidelines for Micro-Scale/Kinetic Modeling

被引：30
|
作者：
Touloupidis, Vasileios [1 ]
机构：
[1] Borealis Polyolefine GmbH, Modeling & Simulat Dept, A-4021 Linz, Austria
来源：
MACROMOLECULAR REACTION ENGINEERING | 2014年 / 8卷 / 07期
关键词：
catalysis; kinetics (polym.); modeling; polyolefins; Ziegler-Natta polymerization; MOLECULAR-WEIGHT DISTRIBUTIONS; ETHYLENE POLYMERIZATION; SLURRY REACTOR; STEADY-STATE; HETEROGENEOUS CATALYSIS; QUANTITATIVE-EVALUATION; METALLOCENE CATALYST; KINETIC CONSTANTS; MASS-TRANSFER; SIMULATION;
D O I：
10.1002/mren.201300188
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The scope of this work is to explain the multi-scale polymerization process modeling framework, comprising of polymerization kinetics (micro-scale), system thermodynamics (meso-scale), and reactor performance (macro-scale) as well as to present the methodology for developing a mathematical model for catalytic olefin polymerization. Guidelines for tuning the kinetic model parameters are proposed. This review aims to provide basic knowledge and understanding regarding catalytic olefin polymerization kinetics and offers the starter-kit tools for developing similar works.
引用
收藏
页码：508 / 527
页数：20
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