A two-dimensional organic-inorganic lead iodide perovskite: poly[bis(3-fluorocyclobutylammonium) [di-μ-iodido-diiodidoplumbate(VI)]]

被引：4
|
作者：
Huang, Chao-Ran [1 ]
Li, Peng-Fei [2 ]
Luo, Xu-Zhong [1 ]
机构：
[1] Gannan Normal Univ, Coll Chem & Chem Engn, Key Lab Organo Phamaceut Chem Jiangxi Prov, Ganzhou 341000, Peoples R China
[2] Nanchang Univ, Ordered Matter Sci Res Ctr, Nanchang 330031, Jiangxi, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2020年 / 76卷
基金：
中国国家自然科学基金;
关键词：
lead iodide perovskite; crystal structure; HOIP; semiconductor; band gap;
D O I：
10.1107/S2053229620015272
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In recent years, great technological advances have been achieved in the growth of hybrid organic-inorganic perovskites (HOIPs) and these have attracted extensive attention due to their optoelectronic properties, structural tunability and stability. We present here a new two-dimensional hybrid organic-inorganic perovskite, namely, poly[bis(3-fluorocyclobutylammonium) [di-mu-iodido-diiodidoplumbate(VI)]], {(C4H9FN)(2)[PbI4]}(n), showing a two-dimensional reticular layer with the organic cations in the middle of the meshes. The calculated experimental band gap is 2.44 eV and the band gap is calculated as 2.20 eV theoretically, which further suggests the potential of this compound as a semiconductor.
引用
收藏
页码：1096 / +
页数：7
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