Ni-Catalyzed Carboxylation of Unactivated Primary Alkyl Bromides and Sulfonates with CO2

被引：0
|
作者：
Liu, Yu [1 ]
Cornella, Josep [1 ]
Martin, Ruben [1 ,2 ]
机构：
[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
[2] Passeig Lluis Co 23, Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 32期
基金：
欧洲研究理事会;
关键词：
CROSS-COUPLING REACTIONS; CARBON-DIOXIDE; REDUCTIVE CARBOXYLATION; ARYL BROMIDES; ZINC HALIDES; REAGENTS; BONDS; ACIDS; ELECTROPHILES; TRANSFORMATION;
D O I：
10.1021/ja05064586
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Ni-catalyzed carboxylation of unactivated primary alkyl bromides and sulfonates with CO2 at atmospheric pressure is described. The method is characterized by its mild conditions and remarkably wide scope without the need for air- or moisture-sensitive reagents, which make it a user-friendly and operationally simple protocol en route to carboxylic acids.
引用
收藏
页码：11212 / 11215
页数：4
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