Facile Thiol-Ene Click Protocol Using Benzil as Sensitizer and White LED as Light Source

被引：12
|
作者：
Das, Anupam [1 ]
Thomas, K. R. Justin [1 ]
机构：
[1] Indian Inst Technol Roorkee, Dept Chem, Organ Mat Lab, Roorkee 247667, Uttar Pradesh, India
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 2020卷 / 46期
关键词：
Alkenes; Alkynes; Thiols; White LED; Green chemistry; PHOTOCATALYTIC INITIATION; POLYMER; CATALYSIS; YNE;
D O I：
10.1002/ejoc.202001275
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The thiol-ene reaction leading to a series of thioether derivatives by simple metal and oxidant free visible light promoted photosensitized protocol, following anti-Markonikov hydrothiolation of unactivated aryl and alkyl olefins at room temperature is demonstrated. Benzil served as a green photosensitizer in this reaction and white LED lights as a light source. This radical based thiol-ene reaction is operationally simple and tolerates a wide variety of functional groups present in olefins.
引用
收藏
页码：7214 / 7218
页数：5
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