Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts

被引：33
|
作者：
Murillo Leo, Inmaculada [1 ]
Lopez Granados, Manuel [1 ]
Garcia Fierro, Jose Luis [1 ]
Mariscal, Rafael [1 ]
机构：
[1] Inst Catalysis & Petrochem CSIC, Grp Sustainable Energy & Chem, Madrid 28049, Spain
来源：
CHINESE JOURNAL OF CATALYSIS | 2014年 / 35卷 / 05期
关键词：
Sorbitol; Glycols; Hydrogenolysis; Ruthenium; Oxide supports; ETHYLENE-GLYCOL; CARBIDE CATALYSTS; DIRECT CONVERSION; CELLULOSE; SURFACE; CHEMISORPTION; HYDROGENATION; SELECTIVITY; GLYCEROL; POLYOLS;
D O I：
10.1016/S1872-2067(14)60086-3
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Supported Ru catalysts were prepared by wet impregnation to evaluate the role of different oxide supports (Al2O3, SiO2, TiO2, ZrO2) in sorbitol hydrogenolysis to glycols. X-ray diffraction, transmission electron microscopy, hydrogen chemisorption, X-ray photoelectron spectroscopy, and NH3 temperature-programmed desorption were used to characterize the catalysts, which were active in the hydrogenolysis of sorbitol. The support affected both the physicochemical properties and catalytic behavior of the supported Ru particles. The characterization results revealed that the Ru/Al2O3 catalyst has a high surface acidity, partially oxidized Ru species on the surface, and a higher surface Ru/Al atomic ratio, which gave it the highest selectivity and yield to glycols. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：614 / 621
页数：8
相关论文
共 50 条
  • [21] Modification of ruthenium catalysts for alkane hydrogenolysis
    Bond, GC
    Hooper, AD
    APPLIED CATALYSIS A-GENERAL, 2000, 191 (1-2) : 69 - 81
  • [22] Glycerol hydrogenolysis over ruthenium supported on lanthanum modified ZrO2 catalysts
    Bo He
    Chuang Li
    Zihui Xiao
    Baowei Wang
    Changhai Liang
    Reaction Kinetics, Mechanisms and Catalysis, 2017, 122 : 101 - 115
  • [23] Hydrogenolysis of Furfuryl Alcohol to 1,2-Pentanediol Over Supported Ruthenium Catalysts
    Yamaguchi, Aritomo
    Murakami, Yuka
    Imura, Tomohiro
    Wakita, Kazuaki
    CHEMISTRYOPEN, 2021, 10 (08): : 731 - 736
  • [24] Glycerol hydrogenolysis over ruthenium supported on lanthanum modified ZrO2 catalysts
    He, Bo
    Li, Chuang
    Xiao, Zihui
    Wang, Baowei
    Liang, Changhai
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2017, 122 (01) : 101 - 115
  • [25] Effect of sulfur and temperature on ruthenium-catalyzed glycerol hydrogenolysis to glycols
    Lahr, DG
    Shanks, BH
    JOURNAL OF CATALYSIS, 2005, 232 (02) : 386 - 394
  • [26] Catalytic hydrogenolysis of sorbitol to glycols over chromium oxide silica: Effect of chromium loading
    Alexzman, Z. A.
    Salamun, N.
    Ibrahim, M. L.
    Sidi, S. M.
    Annuar, N. H. R.
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2024, 12 (03):
  • [27] HYDROGENOLYSIS OF NORMAL-BUTANE ON SUPPORTED RUTHENIUM
    KEMPLING, JC
    ANDERSON, RB
    INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1970, 9 (01): : 116 - &
  • [28] Supported metal catalysts for lignin hydrogenolysis
    Scott, Susannah
    Jones, Zachary
    Wu, Xuejiao
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [29] Sorbitol Hydrogenolysis to Glycols over Carbon Nanofibers/Graphite-felt Composite-supported Ru Catalyst in a Trickle Bed Reactor
    Zhao, L.
    Zhou, J.
    Yang, G.
    Ji, Y.
    Zhang, M.
    Chen, H.
    Zhou, X.
    ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2012, 34 (5-8) : 430 - 438
  • [30] Sorbitol Hydrogenolysis Over Ni, Pt and Ru Supported on NaY
    Banu, M.
    Venuvanalingam, P.
    Shanmugam, R.
    Viswanathan, B.
    Sivasanker, S.
    TOPICS IN CATALYSIS, 2012, 55 (11-13) : 897 - 907
12345