pH-Controlled Assembly of Organophosphonate-Bridged Dysprosium(III) Single-Molecule Magnets Based on Polyoxometalates

被引：36
|
作者：
Huo, Yu [1 ]
Chen, Yan-Cong [1 ]
Wu, Si-Guo [1 ]
Jia, Jian-Hua [1 ]
Chen, Wen-Bin [1 ]
Liu, Jun-Liang [1 ]
Tong, Ming-Liang [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
来源：
INORGANIC CHEMISTRY | 2018年 / 57卷 / 12期
基金：
美国国家科学基金会;
关键词：
BOND-VALENCE PARAMETERS; CHEMICAL-PROPERTIES; DY-3; TRIANGLES; IONIC-RADII; CLUSTERS; COMPLEXES; METAL; MAGNETIZATION; TRANSITION; WHEEL;
D O I：
10.1021/acs.inorgchem.8b00795
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two structurally intriguing dysprosium(III)-substituted polyoxometalates, [Dy-6(ampH)(4)(H2O)(23)(ampH(2))(PW11O39)(2)] (1) and [Dy-9(CO3)(3)(ampH)(2)(H2O)(12)(PW10O37)(6)](35-)(2), are assembled by the same precursor under different pH conditions. The structure of 1 contains an octahedral {Dy-6(ampH)(4)} core, and a unique windmill-type {Dy-9(CO3)(3)(ampH)(2)} for 2. Single-molecule magnet behavior is observed for 2 with a thermally activated energy barrier of 56 K and no appreciable quantum tunneling of magnetization under zero field.
引用
收藏
页码：6773 / 6777
页数：5
相关论文
共 50 条
  • [41] Circularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb(iii) single-molecule magnets
    Mattei, Carlo Andrea
    Montigaud, Vincent
    Lefeuvre, Bertrand
    Dorcet, Vincent
    Argouarch, Gilles
    Cador, Olivier
    Le Guennic, Boris
    Maury, Olivier
    Lalli, Claudia
    Guyot, Yannick
    Guy, Stephan
    Gindre, Cyprien
    Bensalah-Ledoux, Amina
    Riobe, Francois
    Baguenard, Bruno
    Pointillart, Fabrice
    JOURNAL OF MATERIALS CHEMISTRY C, 2023, 11 (22) : 7299 - 7310
  • [42] Strong Antiferromagnetic Exchange-Coupling Observed in Hydride-Bridged Dimeric Dysprosium(III) Single-Molecule Magnet
    Luo, Qian-Cheng
    Yu, Ke-Xin
    Jin, Peng-Bo
    Liu, Ye-Ye
    Zhai, Yuan-Qi
    Zheng, Yan-Zhen
    CHINESE JOURNAL OF CHEMISTRY, 2024, 42 (04) : 391 - 396
  • [43] Double and triple pyridine-N-oxide bridged dinuclear Dysprosium(III) dimers and single-molecule magnetic properties
    Zhang, Ling
    Ma, Hua
    Wang, Zhi-Qiang
    Tian, Yong-Mei
    Zhang, Yi-Quan
    Sun, Wen-Bin
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1175 : 686 - 697
  • [44] A New "Offset" Analogue of the Classical Oxime-Bridged [mn6III] Single-Molecule Magnets
    Poole, Katye M.
    Korabik, Maria
    Shiddiq, Muhandis
    Mitchell, Kylie J.
    Fournet, Adeline
    You, Zhiliang
    Christou, George
    Hill, Stephen
    Holynska, Malgorzata
    INORGANIC CHEMISTRY, 2015, 54 (04) : 1883 - 1889
  • [45] Two Dysprosium(III)-Based Single-Molecule Magnets Derived from 1,10-Phenanthroline Ligands and Different Anions as Bridging Groups
    She, Shixiong
    Su, Gangping
    Wang, Bo
    Lei, Quan
    Yang, Yan
    Gong, Li
    Liu, Beibei
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (18) : 2406 - 2412
  • [46] Integrating Polyoxometalate into Dy(III)-based Single-molecule Magnets with Pentagonal Bipyramidal Symmetry
    Kong, Hui
    Ruan, Ze-Yu
    Chen, Yan-Cong
    Deng, Wei
    Liao, Pei-Yu
    Wu, Si-Guo
    Tong, Ming-Liang
    INORGANIC CHEMISTRY, 2024, 63 (34) : 15964 - 15972
  • [47] A family of cationic oxime-based hexametallic manganese(III) single-molecule magnets
    Martinez-Lillo, Jose
    Dolan, Neil
    Brechin, Euan K.
    DALTON TRANSACTIONS, 2014, 43 (11) : 4408 - 4414
  • [48] Synthesis, structure, magnetic and luminescence properties of two dysprosium single-molecule magnets based on phenoxide dye ligands
    Long, Jerome
    Selikhov, Alexander N.
    Mamontova, Ekaterina
    Lyssenko, Konstantin A.
    Guari, Yannick
    Larionova, Joulia
    Trifonov, Alexander A.
    CRYSTENGCOMM, 2020, 22 (11) : 1909 - 1913
  • [49] From Serendipitous Assembly to Controlled Synthesis of 3d-4f Single-Molecule Magnets
    Ledezma-Gairaud, M.
    Grangel, L.
    Aromi, G.
    Fujisawa, T.
    Yamaguchi, A.
    Sumiyama, A.
    Sanudo, E. C.
    INORGANIC CHEMISTRY, 2014, 53 (12) : 5878 - 5880
  • [50] High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium(III) metallocenium single-molecule magnets
    McClain, K. Randall
    Gould, Colin A.
    Chakarawet, Khetpakorn
    Teat, Simon J.
    Groshens, Thomas J.
    Long, Jeffrey R.
    Harvey, Benjamin G.
    CHEMICAL SCIENCE, 2018, 9 (45) : 8492 - 8503
12345