Molten carbonate fuel cell electrochemistry modelling

被引：17
|
作者：
Bittanti, Sergio
Canevese, Silvia
De Marco, Antonio
Errigo, Antonio
Prandoni, Valter
机构：
[1] Politecn Milan, Dipartimento Elettron & Informaz, I-20133 Milan, Italy
[2] CESI SpA, I-20134 Milan, Italy
[3] CESI RIC SpA, I-20134 Milan, Italy
来源：
JOURNAL OF POWER SOURCES | 2006年 / 160卷 / 02期
关键词：
MCFC; dynamic mathematical model; activated complex;
D O I：
10.1016/j.jpowsour.2006.04.057
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A Fuel Cell (FC) is an electrochemical device which produces electric energy in DC. In order to support design control for the electrical system connected to it, it is necessary to work out a suitable representation of the fast dynamics involved. Therefore, in this work, a mathematical model, based on first principles and including both dynamical equations and algebraic relations, is described for electrochemical reactions, with the related formation of potential differences and anion and cation accumulation phenomena, in a Molten Carbonate Fuel Cell (MCFC). The model is formally consistent and it has been validated against experimental results, such as steady-state power and voltage versus current curves. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：846 / 851
页数：6
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