Induced smectic phase in a nematic liquid crystal mixture

被引:28
|
作者
Kyu, T [1 ]
Chiu, HW [1 ]
Kajiyama, T [1 ]
机构
[1] KYUSHU UNIV,FAC ENGN,HIGASHI KU,DEPT CHEM SCI & TECHNOL,FUKUOKA 812,JAPAN
来源
PHYSICAL REVIEW E | 1997年 / 55卷 / 06期
关键词
D O I
10.1103/PhysRevE.55.7105
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
It has been recognized experimentally that a smectic phase can be induced in a nematic mixture via strong mesogenic interaction. To account for an induced smectic phase boundary, we have developed a theoretical model by combining Flory-Huggins (FH) theory for isotropic mixing and Maier-Saupe-McMillan (MSM) theory for ordering of smectic-A phase (Sm-A) in the nematic mixture, although smectic ordering is forbidden in the constituent pure nematic liquid crystals. The predictive capability of the present combined FH-MSM model for the coexistence curves of the nematic mixture and the concomitant induced smectic phase boundary has been critically tested with the reported induced smectic phase diagrams.
引用
收藏
页码:7105 / 7110
页数:6
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