A one-dimensional chain CdII polymer:: catena-poly[[tris(1H-imidazole-κN3)cadmium(II)]-μ-benzene-1,4-dioxyacetato-κ3O,O′:O"]

被引：18
|
作者：
Gao, S [1 ]
Liu, JW [1 ]
Huo, LH [1 ]
Zhao, H [1 ]
Zhao, JG [1 ]
机构：
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804020409
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title coordination polymer, [Cd(1,4-BDOA)(C3H4N2)(3)](n) (1,4-BDOA2(-) is benzene-1,4-dioxyacetate, C10H8O6), each Cd-II atom exists in a distorted octahedral coordination sphere, involving three carboxyl O atoms from different 1,4-BDOA(2-) groups and three N atoms from the imidazole co-ligands. The Cd-II ions are linked by carboxylate groups into a one-dimensional infinite chain. The Cd...Cd separation within the polymer is 15.009 (2) Angstrom. N-H...O hydrogen bonds help to establish the crystal packing.
引用
收藏
页码：M1308 / M1310
页数：3
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