ENANTIOSELECTIVE RADICAL CYCLIZATION FOR THE SYNTHESIS OF CYCLIC COMPOUNDS

被引:24
|
作者
Yoshioka, Eito [1 ]
Kohtani, Shigeru [1 ]
Miyabe, Hideto [1 ]
机构
[1] Hyogo Univ Hlth Sci, Sch Pharm, Chuo Ku, Kobe, Hyogo 6508530, Japan
关键词
Radical; Cyclization; Enantioselective Reaction; Lewis Acid; Organocatalyst; CHIRAL LEWIS-ACID; CARBON-CARBON BOND; ATOM TRANSFER-REACTIONS; ADDITION-CYCLIZATION; FORMING REACTIONS; TIN HYDRIDE; CONSTRUCTION; ALLYLATION;
D O I
10.3987/REV-08-SR(D)8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review highlights the enantioselective radical cyclization reactions catalyzed by chiral Lewis acid as well as organocatalyst. The results of the radical cyclization controlled by chiral Al, Ti, Mg, Yb and Zn reagents, the oxidative cyclization using chiral amine, the chiral complexing agent-catalyzed reductive cyclization, transfer of chirality in radical cyclization, and so on are summarized.
引用
收藏
页码:229 / 242
页数:14
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