Surface Properties and Active Sites of Nitrided Mo/Al2O3 Catalysts for the Hydrodenitrogenation of Carbazole

被引：7
|
作者：
Ishii, Hiromi [1 ]
Kiyoshi, Masaru [1 ]
Nagai, Masatoshi [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan
来源：
TOPICS IN CATALYSIS | 2009年 / 52卷 / 11期
关键词：
Active sites; Carbazole; Characterization; Hydrodenitrogenation; Molybdenum nitride; SUPPORTED MOLYBDENUM NITRIDE; FT-IR; THIOPHENE HYDRODESULFURIZATION; TUNGSTEN NITRIDE; METAL CARBIDES; ALUMINA; MO; DIBENZOTHIOPHENE; GAMMA-MO2N; AREA;
D O I：
10.1007/s11244-009-9293-2
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The active sites for the hydrodenitrogenation of carbazole for a series of low loading nitrided Mo/Al2O3 catalysts have been investigated by a combination of CO adsorption, pyridine adsorption, temperature-programmed surface reaction with hydrogen and fractal analysis. Accordingly, the active sites for different stages of reaction have been determined. It is proposed that carbazole adsorbs on the edge of molybdenum nitride crystallites where it is hydrogenated to perhydrocarbazole which desorbs, migrating to nitrogen deficient nitrogen planes where it undergoes C-N hydrogenolysis.
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页码：1525 / 1534
页数：10
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