Complexes of a crown ether with gallium(III) iodide and indium(III) iodide

被引：19
|
作者：
Kloo, LA
Taylor, MJ
机构：
[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND
[2] LUND UNIV,DEPT CHEM,S-22100 LUND,SWEDEN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 15期
关键词：
D O I：
10.1039/a701017f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The diethyl ether adducts Et2O . MI3 (M = Ga or In) have been converted by reaction with the macrocyclic ether 1.4,7,10,13,16-hexaoxacyclooctadecane (18-crown-6) into complex ionic products [MI2(18-crown-6)][MI4]. Raman and IR spectra yielded the assignments: for [GaI2](+), nu(1) 161; nu(2) 60; nu(3) 313 cm(-1); for [InI2](+), nu(1) 150, nu(2) 46, nu(3) 258 cm(-1). X-Ray analysis of the indium compound as colourless monoclinic crystals revealed a weakly complexed [InI2](+) cation with In-I 2.617(1) and 2.619(1) Angstrom and an I-In-I angle of 170.14(4)degrees threaded through the cavity of the crown ether, and a distorted tetrahedral [InI4](-) anion with the average In-I bond length of 2.708(2) Angstrom.
引用
收藏
页码：2693 / 2696
页数：4
相关论文
共 50 条
  • [21] THERMOCHEMICAL STUDIES ON THE FORMATION OF AZIDE COMPLEXES OF GALLIUM(III) AND INDIUM(III)
    AVSAR, E
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1982, 36 (08): : 627 - 631
  • [22] Tripodal aminophenolate ligand complexes of aluminum(III), gallium(III), and indium(III) in water
    Caravan, P
    Orvig, C
    INORGANIC CHEMISTRY, 1997, 36 (02) : 236 - 248
  • [23] CHROMIUM(III) IODIDE
    GREGORY, NW
    HANDY, LL
    INORGANIC SYNTHESES, 1957, 5 : 128 - 130
  • [24] DIPHENYLARSENIC(III) IODIDE
    BEGLEY, MJ
    SOWERBY, DB
    SILAGHIDUMITRESCU, L
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 1632 - 1634
  • [25] OSMIUM(III) IODIDE
    SCHAFER, H
    HUNEKE, KH
    BRENDEL, C
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1971, 383 (01): : 49 - &
  • [26] COMPLEXES OF ALUMINIUM(III), GALLIUM(III), AND INDIUM(III) WITH 1,10-PHENANTHROLINE
    SUTTON, GJ
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1963, 16 (02) : 278 - &
  • [27] RHENIUM(III) IODIDE
    MALATESTA, L
    WATT, GW
    THOMPSON, RJ
    INORGANIC SYNTHESES, 1963, 7 : 185 - 189
  • [28] BISMUTH(III) IODIDE
    WATT, GW
    HAKKI, WW
    CHOPPIN, GR
    INORGANIC SYNTHESES, 1953, 4 : 114 - 116
  • [29] Structural variations in cyclopentadienyl uranium(III) iodide complexes
    Wedal, Justin C.
    Windorff, Cory J.
    Huh, Daniel N.
    Ryan, Austin J.
    Ziller, Joseph W.
    Evans, William J.
    JOURNAL OF COORDINATION CHEMISTRY, 2020, 74 (1-3) : 74 - 91
  • [30] Oxidation of iodide by a series of Fe(III) complexes in acetonitrile
    Wang, XG
    Stanbury, DM
    INORGANIC CHEMISTRY, 2006, 45 (08) : 3415 - 3423
12345