Asymmetric rectified electric fields between parallel electrodes: Numerical and scaling analyses

Recent computational and experimental work has established the existence of asymmetric rectified electric fields (AREFs), a type of steady electric field that occurs in liquids in response to an applied oscillatory potential, provided the ions present have different mobilities [Hashemi Amrei et al., Phys. R v. Lett. 121, 185504 (2018)]. Here we use scaling analyses and numerical calculations to elaborate the nature of one-dimensional AREFs between parallel electrodes. The AREF magnitude is shown to increase quadratically with applied potential at low potentials, increase nonlinearly at intermediate potentials, then increase with a constant rate slower than quadratically at sufficiently high potentials, with no impact at any potential on the spatial structure of the AREF. In contrast, the AREF peak location increases linearly with a frequency-dependent diffusive length scale for all conditions tested, with corresponding decreases in both the magnitude and number of sign changes in the directionality of AREF. Furthermore, both the magnitude and spatial structure of the AREF depend sensitively on the ionic mobilities, valencies, and concentrations, with a potential-dependent peak AREF magnitude occurring at an ionic mobility ratio of D-/D+ less than or similar to 5. The results are summarized with approximate scaling expressions that will facilitate interpretation of the steady component for oscillatory fields in liquid systems.