One-step solvent-free synthesis of cyclic carbonates by oxidative carboxylation of styrenes over a recyclable Ti-containing catalyst

被引：51
|
作者：
Maksimchuk, Nataliya V. [1 ,2 ]
Ivanchikova, Irina D. [1 ,3 ]
Ayupov, Artem B. [1 ]
Kholdeeva, Oxana A. [1 ,2 ]
机构：
[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Tomsk State Univ, Tomsk 634050, Russia
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2016年 / 181卷
基金：
俄罗斯基础研究基金会;
关键词：
Carbon dioxide; Cyclic carbonate; Mesoporous titanium-silicate; Oxidative carboxylation; Styrene; CONTAINING MOLECULAR-SIEVES; CHEMICAL FIXATION; ONE-POT; HETEROGENEOUS CATALYSTS; ORGANIC CARBONATES; MESOPOROUS SILICA; TITANIA-SILICA; DIOXIDE; CO2; EPOXIDATION;
D O I：
10.1016/j.apcatb.2015.08.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A mesoporous titanium-silicate prepared by evaporation-induced self-assembly is an efficient heterogeneous catalyst for the one-step oxidative carboxylation of styrenes with tert-butyl hydroperoxide and carbon dioxide in the presence of tetrabutylammonium bromide as cocatalyst under mild solvent-free conditions (50-70 degrees C, 8 bar CO2). The selectivity to cyclic carbonates reaches 69-70% at 92-98.5% substrate conversion. The catalyst can be easily recovered by filtration and reused several times without a significant deterioration of the catalytic performance. The volume yield of SC as high as 1.1 kg/L could be achieved after seven reuses. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：363 / 370
页数：8
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