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Li+ co-doping effect on the photoluminescence time decay behavior of Y2O3:Er3+ films
被引:13
|作者:
Meza-Rocha, A. N.
[1
]
Huerta, E. F.
[2
]
Caldino, U.
[2
]
Zaleta-Alejandre, E.
[1
]
Murrieta S, H.
[3
]
Hernandez, J. M.
[3
]
Camarillo, E.
[3
]
Rivera-Alvarez, Z.
[1
]
Righini, G. C.
[4
,5
,6
]
Falcony, C.
[1
]
机构:
[1] IPN, Ctr Invest & Estudios Avanzados, Dept Fis, Mexico City 07360, DF, Mexico
[2] Univ Autonoma Metropolitana Iztapalapa, Dept Fis, Mexico City 09340, DF, Mexico
[3] Univ Nacl Autonoma Mexico, Inst Fis, Mexico City 01000, DF, Mexico
[4] CNR, Inst Fis Applicata Nello Carrara, I-50019 Florence, Italy
[5] Museo Stor Fis, I-00184 Rome, Italy
[6] Ctr Studi & Ric Enrico Fermi, I-00184 Rome, Italy
关键词:
Charge transfer model;
Extended lifetimes of Er3+ ions;
Enhanced luminescence;
Li+ co-doping;
ENHANCED LUMINESCENCE PROPERTIES;
THIN-FILMS;
PHOSPHORS;
Y2O3-EU3+;
DEFECTS;
D O I:
10.1016/j.jlumin.2014.04.015
中图分类号:
O43 [光学];
学科分类号:
070207 ;
0803 ;
摘要:
The effect of Li+ co-doping on photoluminescence time decay characteristics of Y2O3:Er3+ is reported for films deposited by ultrasonic spray pyrolysis at 500 degrees C. The Er3+ content was fixed at 1.5 at% while the Li+ content in the spraying solution was varied from 1 to 4 at% in relation to Y3+. It is observed that the addition of Li+ content up to 2 at%, besides resulting in an increase of the luminescence emission intensity, modifies the luminescence time decay behavior as well. A simple model in which charge transfer from localized centers to the Er3+ ions is used to describe the evolution with time of the luminescence emission. The introduction of Li+ ions in Y2O3:Er3+ seems to have an impact on the charge transfer process and on the total number of Er3+ ions contributing to the luminescence emission. (C) 2014 Elsevier B.V. All rights reserved.
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页码:106 / 110
页数:5
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