Palladium-Catalyzed Arylboration of Bicyclic Alkenes

被引：44

作者：

Yang, Kai ^{[1
]}

Song, Qiuling ^{[1
,2
]}

机构：

[1] Huaqiao Univ, Coll Chem Engn, Inst Next Generat Matter Transformat, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 81卷 / 03期

基金：

美国国家科学基金会;

关键词：

C-H FUNCTIONALIZATION; COPPER(I)-CATALYZED REACTION; SYNERGISTIC CATALYSIS; ARYLBORONIC ACIDS; ARYL IODIDES; CARBOBORATION; CYCLIZATION; CASCADE;

D O I：

10.1021/acs.joc.5b02564

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A palladium-catalyzed arylboration of norbornene or norbomadiene with aryl halides and bis(pinacolato)diboron has been disclosed. Mechanistic studies suggest that the reaction proceeds under a Catellani-type coupling to render versatile multifunctionalized alkylboranes in good yields. This reaction is complementary to the existing methods and is well tolerable with a variety of functional groups and readily scaled-up to a gram scale without deteriorating the yield.

引用

页码：1000 / 1005

页数：6

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