Self-complementary self-assembly of 3D coordination framework involving d-block, s-block metal ions and flexible NTA3-ligand

被引：9
|
作者：
Li, Hui [1 ]
Tian, Hong [1 ]
Guo, Ming [1 ]
He, Fei Yue [1 ]
Hu, Changwen [1 ]
机构：
[1] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 09期
关键词：
d-block metal ion; s-block metal ion; flexible ligand; nitrilotriacetic acid; coordination framework;
D O I：
10.1016/j.inoche.2006.05.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the flexible ligand nitrilotriacetate with Cu(acac)(2) under hydrothermal condition gave a unique 3D coordination polymer, NaCuNTAH(2)O (NTA(3-) = the anion of nitrilotriacetate). Na+ ion plays an important role in chargeable and structural complementarity in the construction of 3D coordination framework. The unusual coordination mode of NTA ligand has been found for the first time. The complex is an example of coordination polymer containing the d-block, s-block metal ions and NTA(3-) ligand generated by an unusual self-complementary self-assembly process. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：895 / 898
页数：4
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