Development of ansa-Metallocene Catalysts for Isotactic Olefin Polymerization

被引：34
|
作者：
Brintzinger, Hans H. [1 ]
Fischer, David [2 ]
机构：
[1] Univ Konstanz, D-78457 Constance, Germany
[2] Albemarle Corp, Baton Rouge, LA 70801 USA
来源：
POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS | 2013年 / 258卷
关键词：
Activation; ansa-Zirconocene catalysts; Constrained-geometry catalysts; ethene/propene rubbers; Isotactic polypropylene; Linear low-density polyethylene; Molar-mass distribution; Olefin polymerization; Reaction mechanisms; Single-site catalysts; Stereosectivity; BRIDGED TETRAHYDROINDENYL LIGANDS; PROPENE POLYMERIZATION; PROPYLENE POLYMERIZATIONS; ZIRCONOCENE CATALYSTS; METHYLALUMINOXANE CATALYST; CRYSTAL-STRUCTURE; CHAIN TRANSFER; DERIVATIVES; ACTIVATION; COMPLEXES;
D O I：
10.1007/12_2013_215
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The development of ansa-metallocene catalysts is considered along several lines of interest - ansa-metallocene complexes with different ligand frameworks, insights gained with regard to relevant reaction intermediates and contributions of ansa-metallocene catalysts to industrial polymer production - with a view toward the present state of the art in these fields of catalysis research.
引用
收藏
页码：29 / 42
页数：14
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