Dynamical exchange-correlation potentials for an electron liquid

被引:0
|
作者
Qian, ZX [1 ]
Vignale, G [1 ]
机构
[1] Univ Missouri, Dept Phys, Columbia, MO 65211 USA
关键词
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The imaginary parts of the exchange-correlation kernels f(xc)(L,T)(omega) in the longitudinal and transverse current-current response functions of a homogeneous electron liquid are calculated exactly at low frequency, to leading order in the Coulomb interaction. Combining these new results with the previously known high-frequency behaviors of Im f(xc)(L,T)(omega) and with the compressibility and the third moment sum rules, we construct simple interpolation formulas for Im f(xc)(L,T)(omega) in three and two spatial dimensions. A feature of our interpolation formulas is that they explicitly take into account the two-plasmon component of the excitation spectrum: our longitudinal spectrum Im f(xc)(L)(omega) is thus intermediate between the Gross-Kohn interpolation, which ignores the two-plasmon contribution, and a recent approximate calculation by Nifosi, Conti, and Tosi, which probably overestimates it. Numerical results for both the real and imaginary parts of the exchange-correlation kernels at typical electron densities are presented, and compared with those obtained from previous approximations. We also find an exact relation between Im f(xc)(L)(omega) and Im f(xc)(T)(omega) at small omega.
引用
收藏
页数:12
相关论文
共 50 条
  • [21] Exact exchange-correlation potentials from ground-state electron densities
    Kanungo, Bikash
    Zimmerman, Paul M.
    Gavini, Vikram
    NATURE COMMUNICATIONS, 2019, 10 (1)
  • [22] EXCHANGE-CORRELATION POTENTIALS IN SCHOTTKY BARRIERS AND HETEROJUNCTIONS
    GODBY, RW
    SHAM, LJ
    SCHLUTER, M
    PHYSICAL REVIEW LETTERS, 1990, 65 (16) : 2083 - 2083
  • [23] EXCHANGE-CORRELATION POTENTIALS FOR HYDROGEN AT ANY DEGENERACY
    STOLZMANN, W
    KRAEFT, WD
    FROMHOLDTREU, I
    CONTRIBUTIONS TO PLASMA PHYSICS, 1989, 29 (4-5) : 377 - 388
  • [24] Towards accurate exchange-correlation potentials for molecules
    Ingamells, VE
    Handy, NC
    CHEMICAL PHYSICS LETTERS, 1996, 248 (5-6) : 373 - 378
  • [25] UNIVERSAL BEHAVIOR OF EXCHANGE-CORRELATION ENERGY IN ELECTRON-HOLE LIQUID
    VASHISHTA, P
    KALIA, RK
    PHYSICAL REVIEW B, 1982, 25 (10): : 6492 - 6495
  • [26] Dynamic exchange-correlation potentials for the electron gas in dimensionality D=3 and D=2
    Nifosi, R
    Conti, S
    Tosi, MP
    PHYSICAL REVIEW B, 1998, 58 (19) : 12758 - 12769
  • [27] Reconstruction of Exchange-Correlation Potentials from Their Matrix Representations
    Oueis, Yan
    Staroverov, Viktor N.
    JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2022, : 6092 - 6098
  • [28] LOCAL EXCHANGE-CORRELATION POTENTIALS IN SOLIDS AND FREE ATOMS
    KMETKO, EA
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1973, 18 (03): : 455 - 455
  • [29] A Comparison of Exact and Model Exchange-Correlation Potentials for Molecules
    Kanungo, Bikash
    Zimmerman, Paul M.
    Gavini, Vikram
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2021, 12 (50): : 12012 - 12019
  • [30] EFFICIENT EXCITED-STATE EXCHANGE-CORRELATION POTENTIALS
    LU, D
    DELEON, JM
    REHR, JJ
    PHYSICA B, 1989, 158 (1-3): : 413 - 414