Enantioresolution and absolute stereochemistry of o-substituted diphenylmethanols

被引:0
|
作者
Kuwahara, S
Watanabe, M
Harada, N
Koizumi, M
Ohkuma, T
机构
[1] Tohoku Univ, Inst Chem React Sci, Sendai, Miyagi 9808577, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan
来源
ENANTIOMER | 2000年 / 5卷 / 01期
关键词
o-substituted diphenylmethanols; chiral dichlorophthalic acid amide; enantioresolution; HPLC separation; X-ray crystallography; absolute configuration; CD spectra;
D O I
暂无
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
o-Substituted diphenylmethanols were enantioresolved by the method of chiral dichlorophthalic acid amide, yielding enantiopure alcohols. Their absolute configurations were unambiguously determined by X-ray crystallography of chiral dichlorophthalate esters.
引用
收藏
页码:109 / 114
页数:6
相关论文
共 50 条
  • [41] SYNTHESIS AND CONFIGURATIONS OF O-SUBSTITUTED HYDROXIMOYL CHLORIDES - STEREOCHEMISTRY AND MECHANISM OF ALKOXIDE ION SUBSTITUTION AT THE CARBON NITROGEN DOUBLE-BOND
    JOHNSON, JE
    GHAFOURIPOUR, A
    HAUG, YK
    CORDES, AW
    PENNINGTON, WT
    EXNER, O
    JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (07): : 993 - 997
  • [42] A New Approach for the Determination of the Absolute Configuration of Secondary Alcohols by 1H NMR with O-Substituted Mandelate Derivatives
    Chataigner, I.
    Lebreton, J.
    Durand, D.
    Guingant, A.
    Tetrahedron Letters, 39 (13):
  • [43] SPATIAL STRUCTURE OF M-SUBSTITUTED AND O-SUBSTITUTED ISOLOGOUS ARYL CYANATES
    CHMUTOVA, GA
    BAUTINA, IV
    VERESHCHAGIN, AN
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1981, 30 (07): : 1252 - 1256
  • [44] Synthesis of o-substituted benzophenones by Grignard reaction of 3-substituted isocoumarins
    Manivel, P.
    Roopan, S. Mohana
    Khan, F. Nawaz
    JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2008, 53 (03): : 1609 - 1610
  • [45] A Divergent Synthesis of Dihydropyridazinones, N-Substituted Dihydropyrazoles, and O-Substituted Pyrazoles
    Masumoto, Eiichi
    Maruoka, Hiroshi
    Okabe, Fumi
    Nishida, Sho
    Yoshimura, Yuki
    Fujioka, Toshihiro
    Yamagata, Kenji
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2011, 48 (01) : 96 - 104
  • [46] Clay catalysis: Condensation of orthoesters with o-substituted aminoaromatics into heterocycles
    Villemin, D
    Hammadi, M
    Martin, B
    SYNTHETIC COMMUNICATIONS, 1996, 26 (15) : 2895 - 2899
  • [47] Monomeric Iodides of o-Substituted Aryl Gallium and Indium Compounds
    Meller, A.
    Kuemmel, C.
    Noltemeyer, M.
    Zeitschrift fuer Naturforschung. B, Journal of Chemical Sciences, 51 (01):
  • [48] STUDIES ON THE OXIME FORMATION OF STEROID KETONES WITH O-SUBSTITUTED HYDROXYLAMINES
    BODOR, A
    FEY, L
    BREAZU, D
    REVUE ROUMAINE DE CHIMIE, 1980, 25 (9-10) : 1367 - 1374
  • [49] Synthesis of some new o-substituted arylcarbamates and related compounds
    Barbarini, JE
    Rittner, R
    Hoehr, NF
    Suwinski, J
    BIOORGANIC CHEMISTRY, 1997, 25 (01) : 37 - 41
  • [50] New S/O-substituted ferrocenediyl ligands and their metal complexes
    Atkinson, Robert C. J.
    Gibson, Vernon C.
    Long, Nicholas J.
    West, Lara J.
    White, Andrew J. P.
    DALTON TRANSACTIONS, 2006, (29) : 3597 - 3602