Nature and properties of metal cations in aqueous solutions

被引:0
|
作者
Grzybkowski, W. [1 ]
机构
[1] Gdansk Tech Univ, Dept Phys Chem, PL-80952 Gdansk, Poland
来源
POLISH JOURNAL OF ENVIRONMENTAL STUDIES | 2006年 / 15卷 / 04期
关键词
solutions; ionization; cations; solutions structure; hydration; water exchange; hydrolysis; acidity; sea water;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Chemical nature, thermodynamic and kinetic properties of metal cations in aqueous solutions are described and discussed in terms of structural factors controlling physical properties of the systems. The structure of hydrated cations, reaction mechanism of water exchange on the cations, hydrolytic phenomena and acidity of the cations are presented. Correlations between coordination states of the salts in and bulk properties of the solutions are indicated. Elements of aquatic chemistry are presented.
引用
收藏
页码:655 / 663
页数:9
相关论文
共 50 条
  • [21] STRUCTURE OF ALUMINUM CATIONS IN AQUEOUS SOLUTIONS
    FRIPIAT, JJ
    VANCAUWE.F
    BOSMANS, H
    JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (07): : 2458 - &
  • [22] NATURE OF THE SPECIFIC INFLUENCE OF TETRAALKYLAMMONIUM CATIONS IN THE ELECTROREDUCTION OF ORGANIC-MOLECULES IN AQUEOUS-SOLUTIONS
    MAIRANOVSKII, SG
    IGNATEVA, FK
    SOVIET ELECTROCHEMISTRY, 1978, 14 (06): : 750 - 752
  • [23] ADSORPTION OF HEAVY-METAL CATIONS FROM AQUEOUS-SOLUTIONS BY WOOL FIBERS
    BALKOSE, D
    BALTACIOGLU, H
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1992, 54 (04) : 393 - 397
  • [24] Theoretical study of the complexes of tyrosine and tryptophan with biologically important metal cations in aqueous solutions
    Kowalska-Baron, Agnieszka
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2015, 1057 : 7 - 14
  • [25] PULSED NMR-STUDY OF AQUEOUS-SOLUTIONS OF ALKALI-METAL CATIONS
    VENABLE, CW
    MILLER, DM
    PHYSIOLOGICAL CHEMISTRY AND PHYSICS, 1980, 12 (04): : 315 - 322
  • [26] The selectivity of active carbons modified by fullerenes with respect to mixtures of metal cations in aqueous solutions
    Samonin, V. V.
    Nikonova, V. Yu.
    Podvyaznikov, M. L.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 82 (08) : 1376 - 1379
  • [27] Functionalized galactoglucomannan-based hydrogels for the removal of metal cations from aqueous solutions
    Elgueta, Elizabeth
    Sanchez, Julio
    Dax, Daniel
    Xu, Chunlin
    Willfor, Stefan
    Rivas, Bernabe L.
    Gonzalez, Marianela
    JOURNAL OF APPLIED POLYMER SCIENCE, 2016, 133 (41)
  • [28] The selectivity of active carbons modified by fullerenes with respect to mixtures of metal cations in aqueous solutions
    V. V. Samonin
    V. Yu. Nikonova
    M. L. Podvyaznikov
    Russian Journal of Physical Chemistry A, Focus on Chemistry, 2008, 82 : 1376 - 1379
  • [29] Insights into the complexation and oxidation of quercetin and luteolin in aqueous solutions in presence of selected metal cations
    Malacaria, Luana
    Bijlsma, Judith
    Hilgers, Roelant
    de Bruijn, Wouter J. C.
    Vincken, Jean-Paul
    Furia, Emilia
    JOURNAL OF MOLECULAR LIQUIDS, 2023, 369
  • [30] Functionalized galactoglucomannan-based hydrogels for the removal of metal cations from aqueous solutions
    Elgueta, Elizabeth (e.elgueta@cipachile.cl), 1600, John Wiley and Sons Inc (133):