Binary Diffusion Coefficients of 2-Ethyltoluene, 3-Ethyltoluene, and 4-Ethyltoluene in Supercritical Carbon Dioxide

被引：23

作者：

Pizarro, Consuelo ^{[1
]}

Suarez-Iglesias, Octavio ^{[1
]}

Medina, Ignacio ^{[1
]}

Bueno, Julio L. ^{[1
]}

机构：

[1] Univ Oviedo, Dept Ingn Quim & TMA, E-33071 Oviedo, Spain

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2009年 / 54卷 / 05期

关键词：

INFINITE-DILUTION; PREDICTING DIFFUSIVITIES; AROMATIC-COMPOUNDS; SELF-DIFFUSION; LIQUID; FLUID; SOLUTES; EQUATION; BUTYLBENZENE; SOLUBILITIES;

D O I：

10.1021/je800738n

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The binary diffusion coefficients of 2-ethyltoluene, 3-ethyltoluene, and 4-ethyltoluene in supercritical carbon dioxide were determined in a pressure range of (15.0 to 35.0) MPa at temperatures of (313, 323, and 333) K by means of the Taylor-Aris dispersion technique. The influence of pressure, temperature, density, and viscosity on the binary diffusion coefficients was examined, and some general trends were established. The experimental results were compared with the values estimated by several semiempirical equations based on the Stokes-Einstein formula and on the Rough-Hard-Sphere model.

引用

页码：1467 / 1471

页数：5

共 50 条

[21] Diffusion Coefficients of Isobutylbenzene, sec-Butylbenzene, and 3-Methylbutylbenzene in Supercritical Carbon Dioxide
Pizarro, Consuelo
Suarez-Iglesias, Octavio
Medina, Ignacio
Bueno, Julio L.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2013, 58 (07): : 2001 - 2007
[22] Molecular dynamics simulation of diffusion coefficients of naphthalene and 2-naphthol in supercritical carbon dioxide
Iwai, Y
Higashi, H
Uchida, H
Arai, Y
FLUID PHASE EQUILIBRIA, 1997, 127 (1-2) : 251 - 261
[23] Binary diffusion coefficients, partition ratios and partial molar volumes at infinite dilution for β-carotene and α-tocopherol in supercritical carbon dioxide
Funazukuri, T
Kong, CY
Kagei, S
JOURNAL OF SUPERCRITICAL FLUIDS, 2003, 27 (01): : 85 - 96
[24] Binary diffusion coefficients and retention factors for long-chain triglycerides in supercritical carbon dioxide by the chromatographic impulse response method
Kong, CY
Withanage, NRW
Funazukuri, T
Kagei, S
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (05): : 1635 - 1640
[25] Measurements of infinite dilution binary diffusion coefficients of acetylferrocene and 1,1′-diacetylferrocene in supercritical carbon dioxide and in liquid organic solvents
Okubo, Yuuki
Kong, Chang Yi
Sakabe, Junichi
Funazukuri, Toshitaka
JOURNAL OF SUPERCRITICAL FLUIDS, 2021, 177
[26] Measurements of binary diffusion coefficients, retention factors and partial molar volumes for myristoleic acid and its methyl ester in supercritical carbon dioxide
Kong, Chang Yi
Mori, Masakazu
Funazukuri, Toshitaka
Kagei, Seiichiro
ANALYTICAL SCIENCES, 2006, 22 (11) : 1431 - 1436
[27] Measurements of Binary Diffusion Coefficients, Retention Factors and Partial Molar Volumes for Myristoleic Acid and Its Methyl Ester in Supercritical Carbon Dioxide
Chang Yi Kong
Masakazu Mori
Toshitaka Funazukuri
Seiichiro Kagei
Analytical Sciences, 2006, 22 : 1431 - 1436
[28] Measurements of binary diffusion coefficients for some low volatile compounds in supercritical carbon dioxide by input-output response technique with two diffusion columns connected in series
Funazukuri, T
Kong, CY
Kagei, S
FLUID PHASE EQUILIBRIA, 2002, 194 : 1169 - 1178
[29] Measurements of binary diffusion coefficients and partition ratios for acetone, phenol, α-tocopherol, and β-carotene in supercritical carbon dioxide with a poly(ethylene glycol)-coated capillary column
Funazukuri, T
Kong, CY
Murooka, N
Kagei, S
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (12) : 4462 - 4469
[30] Diffusion coefficients of 2-fluoroanisole, 2-bromoanisole, allylbenzene and 1,3-divinylbenzene at infinite dilution in supercritical carbon dioxide
Suarez-Iglesias, Octavio
Medina, Ignacio
Pizarro, Consuelo
Bueno, Julio L.
FLUID PHASE EQUILIBRIA, 2007, 260 (02) : 279 - 286

← 1 2 3 4 5 →