Synthesis and Mechanofluorochromism of 4-[Bis(4-methylphenyl)amino]acetophenone

被引：15
|
作者：
Okoshi, Kenji [1 ]
Nakano, Hideyuki [1 ]
机构：
[1] Muroran Inst Technol, Dept Appl Chem, Muroran, Hokkaido 0508585, Japan
来源：
JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY | 2014年 / 27卷 / 04期
关键词：
mechanofluorochromism; solvatofluorochromism; amorphous molecular material; morphorogy; AMORPHOUS MOLECULAR MATERIALS; REVERSIBLE MECHANOCHROMIC LUMINESCENCE; COMPLEXES;
D O I：
10.2494/photopolymer.27.535
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In order to create a new mechanofluorochromic material, title compound (BMAAP) was designed and synthesized. BMAAP was found to readily form an amorphous glass with a glass transition temperature of 9 degrees C and exhibit solvatofluorochromism in solution. BMAAP was also found to exhibit fluorescence both in crystalline state and in amorphous one and the fluorescence color in amorphous state was different from that in crystalline state. Finally, we have found that BMAAP exhibited mechanofluorochromism and the phenomenon was suggested to be caused by morphological change from crystalline state to amorphous one by mechanical grinding.
引用
收藏
页码：535 / 538
页数：4
相关论文
共 50 条
  • [31] N,N′-bis(4-methylphenyl)-3-oxapentanediamide
    Wen, YH
    Wen, HL
    Li, XM
    Zhang, SS
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O1861 - O1862
  • [32] 4-{2-Methoxy-6-[(4-methylphenyl)iminomethyl]phenoxy}phthalonitrile
    Yazici, Serap
    Akkaya, Abdullah
    Agar, Erbil
    Senel, Ismet
    Buyukgungor, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O1172 - U3386
  • [33] 4-[(Hydroxy)(4-methylphenyl)methylidene]isochroman-1,3-dione
    Abou, Akoun
    Djande, Abdoulaye
    Saba, Adama
    Chiavassa, Thierry
    Kakou-Yao, Rita
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O3 - +
  • [34] 2-{(4-Methylphenyl)sulfonyl]amino}-phenyl 4-methylbenzenesulfonate
    Morgans, G. L.
    Scalzullo, S. M.
    Fernandes, M. A.
    Michael, J. P.
    van Otterlo, W. A. L.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2007, 63 (o309-o311): : O309 - O311
  • [35] 4-(4-Methylphenyl)-3-phenyl-4H-1,2,4-triazole
    Chinnakali, K
    Fun, HK
    Senthilvelan, A
    Sriraghavan, K
    Ramakrishnan, VT
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1136 - 1138
  • [36] 4-(4-Methylphenyl)-3-phenyl-4H-1,2,4-triazole
    Chinnakali, Kandasamy
    Fun, Hoong-Kun
    Senthilvelan, Annamalai
    Sriraghavan, Kamaraj
    Ramakrishnan, Vayalakkavoor T.
    Acta Crystallographica, Section C: Crystal Structure Communications, 1999, 55 (07): : 1136 - 1138
  • [37] 1-Amino-5-(4-methylbenzoyl)-4-(4-methylphenyl)pyrimidin-2(1H)-one
    Yildirim, Sema Ozturk
    Ozpozan, Nilgun
    Butcher, Ray J.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3309 - U584
  • [38] Reversible colour changes of mixed films composed of 4,4'-bis[bis(4-methylphenyl)amino]azobenzene and organic acids in response to exhaled breath
    Kitamura, Yuya
    Ichikawa, Ryoji
    Nakano, Hideyuki
    MATERIALS CHEMISTRY FRONTIERS, 2018, 2 (01) : 90 - 95
  • [39] 4-methylphenyl benzyl sulfone
    Li, YS
    Su, WK
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O2450 - O2451
  • [40] 2′,4′-dihydroxy-2-[3-(4-methylphenyl)isoxazol-5-yl]acetophenone
    Kumar, N
    Roy, S
    Parmar, VS
    Errington, W
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1123 - 1125
12345