catena-poly[[tri-n-butyl-tin(IV)]-μ-cyclo-pent-2-enyl-acetato-κ2O:O′]

被引：0
|
作者：
Ahmad, Aftab
Khan, Azim
Ali, Saqib
Parvez, Masood
机构：
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
[2] Gomal Univ, Dept Chem, Dera Ismail Khan, Pakistan
[3] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806015194
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Sn(C4H9)(3)(C7H9O2)](n), forms a polymeric chain involving both O atoms of the carboxyl-ate group. The Sn atom is five-coordinate and shows a distorted trigonal-bipyramidal geometry wherein the C alpha atoms of the n-butyl chains occupy the equatorial positions. Two O atoms from symmetry-related ligands are asymmetrically bonded to the Sn atom and occupy axial positions with significantly different Sn-O distances of 2.209 (2) and 2.358 (2) angstrom.
引用
收藏
页码：M1192 / M1194
页数：3
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