PHYSICOCHEMICAL PROPERTIES OF RUBBER COMPOSITIONS VULCANIZED BY POLYMERIC SULFUR

被引:1
|
作者
Znak, Z. O. [1 ]
Olenych, R. R. [1 ]
机构
[1] Lvivska Politekhnika Natl Univ, Lvov, Ukraine
关键词
polymeric sulfur; plasmolysis of hydrogen sulfide; rubber; vulcanization; cross-linking network; migration of sulfur;
D O I
10.1007/s11003-016-9972-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We study the physicochemical properties of rubbers vulcanized by polymeric and rhombic sulfur and determine the structural parameters of their cross-linking networks. It is shown that vulcanizates based on polymeric sulfur obtained as a result of plasma-chemical decomposition of hydrogen sulfide surpass rubbers vulcanized by rhombic sulfur by the main physicomechanical characteristics. It is shown that the migration of sulfur onto the surfaces of rubbers vulcanized by polymeric sulfur does not occur.
引用
收藏
页码:407 / 413
页数:7
相关论文
共 50 条
  • [21] Determination of true free sulfur in vulcanized rubber - A modification of the thiocyanate method
    Minatoya, S
    Aoe, I
    Nagai, I
    INDUSTRIAL AND ENGINEERING CHEMISTRY-ANALYTICAL EDITION, 1935, 7 : 0414 - 0416
  • [22] Effect of the content of ethyl cellulose-rubber blend on physicochemical properties of adhesive compositions
    V. V. Myasoedova
    L. R. Lyusova
    S. V. Kotova
    V. A. Optov
    A. N. Shchegolikhin
    Polymer Science. Series D, 2008, 1 (3) : 154 - 157
  • [23] Influence of Carbon Black, Calcium Carbonate and Dioctyl Phthalate Compositions on the NBR Vulcanized Rubber Properties Through Experiments Design
    Correia, Sivaldo L.
    Palaoro, Denilso
    Mautone, Andre
    Segadaes, Ana M.
    MACROMOLECULAR SYMPOSIA, 2012, 319 (01) : 161 - 166
  • [24] Influence of the microstructure of vulcanized polybutadiene rubber on the dielectric properties
    Rodriguez Garraza, A. L.
    Sorichetti, P.
    Marzocca, A. J.
    Matteo, C. L.
    Monti, G. A.
    POLYMER TESTING, 2011, 30 (06) : 657 - 662
  • [25] Properties of rubber compounds containing powdered vulcanized waste
    Ogunniyi, DS
    Mureyani, M
    IRANIAN POLYMER JOURNAL, 2001, 10 (03) : 143 - 147
  • [26] INFLUENCE OF CHEMICAL STRUCTURE ON DYNAMIC PROPERTIES OF SULFUR-VULCANIZED, CARBON BLACK-REINFORCED NATURAL RUBBER
    DOYLE, GM
    HUMPHREY.RE
    JOURNAL OF APPLIED POLYMER SCIENCE, 1971, 15 (08) : 1855 - &
  • [27] Properties of rubber compounds containing powdered vulcanized waste
    Ogunniyi, D.S.
    Mureyani, M.
    Iranian Polymer Journal (English Edition), 2001, 10 (03): : 143 - 147
  • [28] PROPERTIES OF RUBBER VULCANIZED UNDER HIGH-PRESSURE
    ISAYEV, AI
    KOCHAR, LS
    RUBBER CHEMISTRY AND TECHNOLOGY, 1986, 59 (01): : 168 - 168
  • [29] C-13 NMR RELAXATION OF SULFUR VULCANIZED NATURAL-RUBBER
    ANDREIS, M
    KOENIG, JL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 75 - POLY
  • [30] Determination of true free sulfur and true coefficient of vulcanization in vulcanized rubber - II
    Kelly, WJ
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY-US, 1922, 14 : 196 - 197