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- [21] Zirconium and hafnium diene and dienyl half-sandwich complexes: synthesis, polymerization catalysis and deactivation pathways. The molecular structures of [M(eta(3)-C3H5)(2,3-Me2C4H4){eta-C5H3(SiMe3)(2)-1,3}](M=Zr or Hf) and [Hf(eta(3)-C3H5){eta(3)-CH2CMeCMeCH2B-(C6F5)(3)}{eta-C5H3(SiMe2)-1,3}] JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (18): : 3115 - 3127