Highly active self-immobilized FI-Zr catalysts in a PCP framework for ethylene polymerization

被引：19
|
作者：
Li, He [1 ]
Xu, Bo [1 ]
He, Jianghao [1 ]
Liu, Xiaoming [1 ]
Gao, Wei [1 ]
Mu, Ying [1 ]
机构：
[1] Jilin Univ, State Key Lab Supramol Struct & Mat, Sch Chem, Changchun 130012, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 93期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS;
D O I：
10.1039/c5cc06460k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of zirconium-based porous coordination polymers (PCPs) containing FI catalysts in the frameworks have been developed and studied as catalysts for ethylene polymerization. These PCPs exhibit good catalytic activities and long life times, producing polyethylenes with high molecular weights and bimodal molecular weight distribution in the form of particles.
引用
收藏
页码：16703 / 16706
页数：4
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