Homoleptic octahedral coordination of CH3CN to Mg2+ in the Mg[N(SO2CF3)2]2-CH3CN system

被引：9
|
作者：
Veryasov, Gleb [1 ]
Matsumoto, Kazuhiko [1 ]
Hagiwara, Rika [1 ]
机构：
[1] Kyoto Univ, Grad Sch Energy Sci, Dept Fundamental Energy Sci, Sakyo Ku, Kyoto 6068501, Japan
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 07期
基金：
日本学术振兴会;
关键词：
BIS(TRIFLUOROMETHANESULFONYL) IMIDE ANION; IONIC LIQUID; MAGNESIUM; ELECTROLYTE; COMPLEXES; IDENTIFICATION; (CF3SO2)(2)NH; STABILITY; BATTERIES; CRYSTAL;
D O I：
10.1039/c5dt04821d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
X-ray diffraction and Raman spectroscopic measurements revealed a homoleptic octahedral coordination of CH3CN to Mg2+ in the [Mg(CH3CN)(6)][TFSA](2) (TFSA = bis(trifluoromethylsulfonyl)imide) crystal structure and in Mg[TFSA](2)/CH3CN electrolytes.
引用
收藏
页码：2810 / 2813
页数：4
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