An unexpected zinc coordination polymer formed during the preparation of 5-substituted 1H-tetrazoles from a nitrile in water

被引：63
|
作者：
Xue, X
Abrahams, BF [1 ]
Xiong, RG
You, XZ
机构：
[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia
[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 08期
关键词：
D O I：
10.1071/CH02089
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of N, N'-dicyanohydrazine with ZnCl2 and NaN3 in water unexpectedly affords 5-aminotetrazolato hydroxo zinc rather than a zinc complex with bis(tetrazolyl) hydrazine. An N-N bond cleavage has occurred in the Demko-Sharpless' tetrazole synthesis.
引用
收藏
页码：495 / 497
页数：3
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