Neutron diffraction studies of the Ba3Ca1+yNb2-yO9-δ+xD2O high-temperature proton conductor

被引:8
|
作者
Sosnowska, I
Schäfer, W
Przenioslo, R
Lind, K
Hempelmann, R
机构
[1] Univ Warsaw, Inst Expt Phys, PL-00681 Warsaw, Poland
[2] Univ Bonn, Inst Mineral, D-53117 Bonn, Germany
[3] Univ Saarlandes, D-66123 Saarbrucken, Germany
来源
PHYSICA B | 2000年 / 276卷
关键词
ceramics; perovskite compounds; phase transitions; diffraction; disordered materials;
D O I
10.1016/S0921-4526(99)01313-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Recently, a new long-range order was observed in the Ba3Ca1.18Nb1.82O9-delta + xD(2)O proton conductor, where x not equal 0. In order to get more information concerning atomic arrangements in these complex perovskite oxides systematic neutron and X-ray diffraction studies of the stoichiometric and non-stiochiometric compound with and without D2O were performed. Oxygen positions and oxygen concentration were determined. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:864 / 865
页数:2
相关论文
共 50 条
  • [21] THERMODYNAMIC STUDIES OF THE HIGH-TEMPERATURE SUPERCONDUCTOR BA2TMCU3O7
    ATAKE, T
    KAWAJI, H
    TAKANABE, S
    SAITO, Y
    MORI, K
    SAEKI, Y
    THERMOCHIMICA ACTA, 1989, 139 : 169 - 179
  • [22] The high temperature proton conductor Ba3Ca1.18Nb1.82O9-δ -: Part II:: electrochemical cell measurements and TEM
    Schober, T
    Bohn, HH
    Mono, T
    Schilling, W
    SOLID STATE IONICS, 1999, 118 (3-4) : 173 - 178
  • [23] NEUTRON-DIFFRACTION STUDIES OF THE HIGH-TEMPERATURE PHASE OF LITA3O8
    MAREZIO, M
    SANTORO, A
    ROTH, RS
    MINOR, D
    ACTA CRYSTALLOGRAPHICA SECTION A, 1978, 34 : S175 - S175
  • [24] Neutron powder diffraction studies on Ba3Ca1+xNb2-xO9-3x/2-complex perovskite-type oxides
    Oikawa, K
    Kamiyama, T
    Ikeda, S
    Shishido, T
    Yamaguchi, S
    SOLID STATE IONICS, 2002, 154 : 641 - 646
  • [25] Pulsed neutron diffraction studies of RO•xB2O3 glasses:: R=Ca, Sr and Ba;: x=2, 3 and 4
    Suzuki, Y
    Ohtori, N
    Takase, K
    Handa, K
    Itoh, K
    Fukunaga, T
    Umesaki, N
    PHYSICS AND CHEMISTRY OF GLASSES, 2003, 44 (02): : 150 - 154
  • [26] POWDER PROCESSING OF HIGH-TEMPERATURE CERAMIC SUPERCONDUCTOR TL2BA2CA2CU3O10
    XIN, Y
    XU, BR
    HE, WS
    SUN, GF
    FARR, R
    LU, DF
    WONG, KW
    KNAPP, D
    JOURNAL OF ELECTRONIC MATERIALS, 1995, 24 (12) : 1821 - 1824
  • [27] Valence and thallium charge in high-temperature Tl2Ba2Ca2Cu3O10 superconductors
    Smirnov, YP
    Sovestnov, AE
    Trzhaskovskaya, MB
    Tyunis, AV
    Shaburov, VA
    FIZIKA TVERDOGO TELA, 1994, 36 (12): : 3613 - 3617
  • [28] Doping effects on complex perovskite Ba3Ca1.18Nb1.82O9-δ intermediate temperature proton conductor
    Wang, Siwei
    Zhao, Fei
    Zhang, Lingling
    Brinkman, Kyle
    Chen, Fanglin
    JOURNAL OF POWER SOURCES, 2011, 196 (19) : 7917 - 7923
  • [29] High-temperature in situ neutron powder diffraction study of monoclinic Tl2Ba2CuO6+δ
    Pederzolli, DR
    Attfield, JP
    INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2000, 2 (06): : 533 - 541
  • [30] The high-temperature proton Ba-3(Ca1.18Nb1.82)O-9-delta: Thermogravimetry of the water uptake
    Krug, F
    Schober, T
    SOLID STATE IONICS, 1996, 92 (3-4) : 297 - 302