Free radical addition reactions of allylic sulfones to alkenes

被引：24
|
作者：
Harvey, IW [1 ]
Phillips, ED [1 ]
Whitham, GH [1 ]
机构：
[1] UNIV OXFORD,DYSON PERRINS LAB,OXFORD OX1 3QY,ENGLAND
来源：
TETRAHEDRON | 1997年 / 53卷 / 18期
关键词：
D O I：
10.1016/S0040-4020(97)00306-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Intermolecular radical reactions involving format addition of the sulfonyl and allyl fragments of an allylic sulfone across the double bond of an alkene are described. Reactions are most successful when the allylic sulfone has an electron withdrawing group at the 2-position. Only monosubstituted alkenes give useful yields of adducts, though both electron withdrawing and electron donating substituents are effective. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：6493 / 6508
页数：16
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