A one-dimensional nickel(III) chain complex showing ferromagnetic ordering: Crystal structure and magnetic property

被引：9
|
作者：
Xie, JL
Ren, XM
Gao, S
Meng, QJ [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
来源：
CHEMISTRY LETTERS | 2002年 / 06期
关键词：
D O I：
10.1246/cl.2002.576
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ferromagnetic complex [BrFBzPy][Ni(mnt)(2)], where [BrFBzPy]' = 1-(4'-bromo-2'-fluorobenzyl)pyridinium and mnt(2-) = maleonitriledithiolate, has been prepared. The [Ni(mnt)(2)](-) anions and [BrFBzPy](+) cations form a well-separated stacking column and [Ni(mnt)(2)](-) anions are uniformly spaced to give a one-dimensional (1-D) chain structure. Its magnetization studies shown it ferromagnetically ordered around 2 K.
引用
收藏
页码：576 / 577
页数：2
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