A new phase transfer reagent for the addition of dichlorocarbene to olefins under mild PTC conditions

被引:19
|
作者
Jayachandran, JP
Wang, ML [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 300, Taiwan
[2] Natl Chung Cheng Univ, Dept Chem Engn, Chiayi 621, Taiwan
关键词
D O I
10.1080/00397919908085884
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A three-step synthetic route to a novel water soluble phase transfer reagent, Diquat (Dq-Br), viz., 2-benzilidine-N,N,N,N',N',N'-hexaethyl propane-1,3 diammonium dibromide and its utility in various dichlorocarbenations to olefins are described.
引用
收藏
页码:4101 / 4112
页数:12
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