Nanostructuring of C60 fullerene thin films

被引：32
|
作者：
Deutsch, D
Tarábek, J
Krause, M
Janda, P
Dunsch, L
机构：
[1] IFW, Leibniz Inst Solid State, D-01069 Dresden, Germany
[2] IFW, Mat Res Dresden, D-01069 Dresden, Germany
[3] J Heyrovsky Inst Phys Chem, Prague 18223 8, Czech Republic
来源：
CARBON | 2004年 / 42卷 / 5-6期
关键词：
fullerenes; thin films; nanostructuring; ionic liquids; FTIR;
D O I：
10.1016/j.carbon.2003.12.038
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Highly ordered C-60 layers prepared on mica and HOPG (highly ordered pyrolytic graphite) substrates by physical vapour deposition were nanostructured by different electrochemical procedures using ionic liquid (1-butyl-3-methyl-imidazolium tetrafluoroborate) as electrolyte. The topology of the films is completely changed and a tenfold larger cluster size than in aqueous solutions was obtained. The most homogeneous films were obtained when lithium trifluoromethanesulfonate was added to the ionic liquid. FTIR spectroscopy was used to study the molecular structure of the nanostructured fullerene films. (C) 2004 Published by Elsevier Ltd.
引用
收藏
页码：1137 / 1141
页数：5
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