Bisthiadiazole-Fused Tetraazapentacenequinone: An Air-Stable Solution-Processable n-Type Organic Semiconductor

被引：26

作者：

Cortizo-Lacalle, Diego ^{[1
]}

Gozalvez, Cristian ^{[1
]}

Olano, Mikel ^{[1
]}

Sun, Xiangnan ^{[2
]}

Melle-Franco, Manuel ^{[3
]}

Hueso, Luis E. ^{[2
,4
]}

Mateo-Alonso, Aurelio ^{[1
,4
]}

机构：

[1] Univ Basque Country UPV EHU, POLYMAT, E-20018 Donostia San Sebastian, Spain

[2] CIC NanoGUNE Consolider, E-20018 Donostia San Sebastian, Spain

[3] Univ Minho, Ctr ALGORITMI, P-4710057 Braga, Portugal

[4] Basque Fdn Sci, Ikerbasque, E-48011 Bilbao, Spain

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 23期

关键词：

FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; PENTACENE DERIVATIVES; PHENAZINE DERIVATIVES; HETEROACENES; AZAACENES; ELECTRON; ACENES; BASES; TRANSPORT;

D O I：

10.1021/acs.orglett.5b03099

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterization of a tetraazapentacene-quinone fused to two thiadiazoles is reported. This linear derivative constituting seven fused rings shows a very low LUMO level (-4.46 eV) and a low HOMO-LUMO gap (1.77 eV). Its high solubility, endowed by four triisopropylsilyl groups, allows the fabrication of air-stable field-effect transistors by liquid deposition methods that show electron mobilities up to 2.42 X 10(-3) cm(2) V-1 s(-1) without any device optimization.

引用

页码：5902 / 5905

页数：4

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