Synthesis and study of trinuclear Pd(II) and Pt(II) complexes with 2-mercaptonicotinic acid -: Crystal and molecular structure of [Pd3(mercaptonicotinic acid)3Cl3]

被引：41

作者：

Marchal, S

Moreno, V

Aullón, G

Alvarez, S

Quirós, M

Font-Bardia, M

Solans, X

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[2] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

[3] Univ Barcelona, Dept Cristallog Mineral & Diposits Minerals, E-08028 Barcelona, Spain

来源：

POLYHEDRON | 1999年 / 18卷 / 27期

关键词：

mercaptonicotinic acid complexes; crystal structure Pd(II) mercaptonicotinic complex; trinuclear palladium complex; trinuclear platinum complex; density functional calculations;

D O I：

10.1016/S0277-5387(99)00303-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd(II) and Pt(II) complexes of 2-mercaptonicotinic acid of formulae [M-3(mercaptonicotinic acid)(3)Cl-3] were synthesized and characterized by the usual spectroscopic techniques including mass spectrometry. The crystal structure was obtained for the palladium complex. The molecule has a ternary symmetry, and mercaptonicotinic acid coordinates in a bidentate (N,S) mode to each palladium ion. The sulfur atom acts as a bridge between two palladium atoms. The fourth coordination site in the plane square geometry of the Pd(II) is occupied by a chloride ion. Identical molecular structure is proposed for the platinum compound in agreement with the spectroscopic and theoretical results. (C) 1999 Elsevier Science Ltd. AII rights reserved.

引用

页码：3675 / 3682

页数：8

共 50 条

[31] Crystal structure and absolute configuration of the palladium(II) pinenyl complex Pd(II)[Pd(η3-β-C10H15) (PPh3)Cl]
Minacheva, L.Kh.
Polyakova, L.A.
Golovaneva, I.F.
Klyagina, A.P.
Gubin, S.P.
Zhurnal Neorganicheskoj Khimii, 2001, 46 (11): : 1822 - 1828
[32] SYNTHESIS AND STRUCTURE OF THE TRINUCLEAR PALLADIUM CLUSTER [PD3(PET3)3(MU-2-NPH)2(MU-2-NHPH)]CL, CONTAINING BRIDGING IMIDO AND AMIDO LIGANDS
LEE, SW
TROGLER, WC
INORGANIC CHEMISTRY, 1990, 29 (05) : 1099 - 1102
[33] Synthesis of Pd(II) complexes containing the protonated form or molecule of 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline (L). The crystal structure of [Pd(HL)Cl3]
Savel'eva, Z. A.
Glinskaya, L. A.
Popov, S. A.
Klevtsova, R. F.
Tkachev, A. V.
Larionov, S. V.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (09) : 668 - 673
[34] Synthesis of Pd(II) complexes containing the protonated form or molecule of 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline (L). The crystal structure of [Pd(HL)Cl3]
Z. A. Savel’eva
L. A. Glinskaya
S. A. Popov
R. F. Klevtsova
A. V. Tkachev
S. V. Larionov
Russian Journal of Coordination Chemistry, 2009, 35 : 668 - 673
[35] Halfantiperovskites II:: on the crystal structure of Pd3Bi2S2
Weihrich, R
Anusca, I
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (02): : 335 - 342
[36] Complexes of 1-hydroxopyridine-2-thione (LH) with Rh(III), Pd(II), Cd(II) and Hg(II):: crystal structure of Pd(L)2 • CHCl3
Anacona, J. R.
Leon, Edgar
Diaz-Delgado, Graciela
JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (13) : 2142 - 2149
[37] Mixed complexes of Pt(II) and Pd(II) with ethylsarcosinedithiocarbamate and 2-/3-picoline as antitumor agents
Giovagnini, L
Marzano, C
Bettio, F
Fregona, D
JOURNAL OF INORGANIC BIOCHEMISTRY, 2005, 99 (11) : 2139 - 2150
[38] Palladium(II) complexes with 8-quinolinethiol:: Structure of trinuclear palladium 2-methylthio-8-quinolinethiolate Pd3[C9H5(SCH2)NS]3
Silin', EY
Bankovskii, YA
Bel'skii, VK
Stash, AI
Pech, LY
Leeis, YE
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2001, 46 (08) : 1184 - 1190
[39] Palladium(II) complexes with 8-quinolinethiol: Structure of trinuclear palladium 2-methylthio-8-quinolinethiolate Pd3[C9H5(SCH2)NS]3
Silin', E.Ya.
Bankovskij, Yu.A.
Belsky, V.K.
Stash, A.I.
Pech, L.Ya.
Leeis, Ya.E.
Zhurnal Neorganicheskoj Khimii, 2001, 46 (08): : 1317 - 1324
[40] AGOSTIC PD...H+...NHR2 AND APICAL PD...NHR2 INTERACTIONS - THE SYNTHESIS AND STRUCTURES OF [PD(II)CL2(H[9]ANEN3)]+, THE PD(II)-PD(II) DIMER [(H[9]ANEN3)CL2PD-PDCL2(H[9]ANEN3)]2+, AND [PD(ME3[9]ANEN3)(NCME)2]2+
BLAKE, AJ
HOLDER, AJ
ROBERTS, YV
SCHRODER, M
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) : 260 - 262

← 1 2 3 4 5 →