Highly efficient photochemical generation of o-quinone methide from Mannich bases of phenol derivatives

被引：71
|
作者：
Nakatani, K [1 ]
Higashida, N [1 ]
Saito, I [1 ]
机构：
[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM & BIOL CHEM,KYOTO 60601,JAPAN
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 28期
关键词：
D O I：
10.1016/S0040-4039(97)01071-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
o-Quinone methide was efficiently produced by photoirradiation of phenolic Mannich bases in aqueous acetonitrile with low energy UV light. The photoreaction proceeds most effectively at neutral pH in aqueous solvents. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：5005 / 5008
页数：4
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