A new hybrid zinc phosphite with a pillared layered structure: Synthesis and characterization of [C6N2O2H16][Zn(HPO3)]2

被引：10

作者：

Wang, Guo-Ming ^{[1
]}

Zhang, Xiao ^{[1
]}

Li, Jin-Hua ^{[1
]}

Wang, Zong-Hua ^{[1
]}

Wang, Ying-Xia ^{[2
]}

Lin, Jian-Hua ^{[2
]}

机构：

[1] Qingdao Univ, Teachers Coll, Coll Chem Chem Engn & Environm, Qingdao 266071, Shandong, Peoples R China

[2] Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷

关键词：

Zinc phosphite; Hybrid material; Hydrothermal synthesis; Helical chains; Crystal structure; 24-RING CHANNELS; HYDROTHERMAL SYNTHESIS; HELICAL CHAINS; FRAMEWORK; ZEOLITES;

D O I：

10.1016/j.inoche.2013.08.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By using flexible 1,2-bis(2-aminoethoxy)ethane (BAEOE) as a pillaring ligand, a new inorganic-organic hybrid open-framework zinc phosphite, [C6N2O2H16][Zn(HPO3)](2) (1), has been hydrothermally synthesized and structurally characterized by IR, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffractions. The structure of 1 consists of neutral layers of zinc phosphite which are further pillared through linear BAEOE ligands, generating a 3D framework with unusual (3, 4)-connected dmc topology. The participation of left-handed and right-handed helical chains in the construction of puckered sheet structure with 4.8(2)-net is also noteworthy. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：27 / 30

页数：4

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