Phase equilibria in the Li2O-B2O3 system

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作者
Kaplun, AB [1 ]
Meshalkin, AB [1 ]
机构
[1] Russian Acad Sci, Inst Thermophys, Siberian Div, Novosibirsk 630090, Russia
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T [工业技术];
学科分类号
08 ;
摘要
Phase equilibria in the Li2O-B2O3 system were studied in the composition range from 48 to 83 mol % B2O3. The liquidus temperatures were determined with a high accuracy for 25 compositions, and the temperatures of invariant equilibria were evaluated. Experimental data on melt supercooling were used to construct a metastable liquidus above the peritectic temperatures. It is shown that the peritectically forming compounds LiB3O5 and Li4B10O17 can, under certain conditions, melt congruently.
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页码:1154 / 1158
页数:5
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