PAH-profiles in sediment cores from the Baltic Sea

To document the historical input the PAH-profiles of sediment cores in two different basins of the Baltic Sea, the Gotland Basin (GB) and Arkona Basin (AB), were analysed by means of GC-MS, 35 PAHs were quantified in all samples, and additionally, several marker PAHs, like Cyclopenta[cd]phenanthrene (CCP) for combustion processes and retene for terrigenous input, were quantified in selected samples. The preindustrial sediments (older than 200-250 years) in the GB core illustrate concentrations <100 ng PAH(35) g(-1) d.w. Calculated PAH-ratios indicated combustion processes a the Main sources for both basins. The Perylene concentrations within the sediment cores decrease with increasing depth. along with an increase in relative percentage. indicating slow diagenetic processes. The preservation and enrichment of the introduced PAHs was more pronounced in the GB core. (C) 2002 Elsevier Science Ltd. All rights reserved.